5-硝基-1-萘甲腈
| 5-硝基-1-萘甲腈 | |
|---|---|
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| 識別 | |
| CAS號 | 23245-64-9 
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| SMILES |
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| 性質 | |
| 化學式 | C11H6N2O2 |
| 摩爾質量 | 198.18 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
5-硝基-1-萘甲腈是一種有機化合物，化學式為C11H6N2O2。它可由1-溴-5-硝基萘和氰化亞銅在二甲基甲酰胺中反應製得[1]，或由1-萘甲腈直接硝化製得，但後者反應會生成8-硝基副產物[2]。在鈀催化下，它可以被氫氣還原為5-氨基-1-萘甲腈[1]。
參考文獻
[編輯]- ^ 1.0 1.1 Shen, Yan-Ming; Song, Lin-Lin; Qian, Xu-Hong; Yang, You-Jun. A scalable synthesis of 1-amino-5-cyanonaphthalene, a precursor for a nitric oxide probe (NO550) designed via the “dye assembly” principle. Chinese Chemical Letters. 2013-01, 24 (1): 7–8. doi:10.1016/j.cclet.2013.01.019.
- ^ Peng, Xinhua; Fukui, Naoyuki; Mizuta, Masayuki; Suzuki, Hitomi. Nitration of moderately deactivated arenes with nitrogen dioxide and molecular oxygen under neutral conditions. Zeolite-induced enhancement of regioselectivity and reversal of isomer ratios. Organic & Biomolecular Chemistry. 2003, 1 (13): 2326. doi:10.1039/B301847D.